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Developing New Multi-modal Polypropylene Random Copolymer (PP-R) Pipe Grades To Meet New Market Needs

Antti Tynys, Cristian Hedesiu

Papers # 2014 Chicago

In the Middle East propylene random copolymers (PP-R) are commonly used for heating, plumbing and domestic water systems in large, prestigious high rise buildings. These buildings may contain more than 60-80 floors and be over 300 metres in height, which demands many kilometres of pipe in sizes up to 160 mm in diameter. Good processability is therefore essential to manufacture these large diameter pipes efficiently and economically without forfeiting any of the materials excellent properties which pushes the design of the existing materials to the limit. Some specific projects in the Middle East are described to illustrate this situation. Initially, unimodal PP-R grades were widely used but due to limitations in the balance between mechanical performance and processability they have been largely replaced by second generation bimodal PP-R grades, which are now widely used in Europe and the Middle East. To address the higher demands for large diameter pipes, further development has led to a third generation multi-modal PP-R material, which shows an excellent balance between mechanical properties and processability. This improved material enables higher output for pipe extrusion and injection moulding fittings whilst maintaining good quality and surface appearance of final product. The authors describe the effect of polymer modality on pipe and fittings performance and processability. In the second part of the paper the authors examine the benefits of alpha nucleation on these materials. It is shown that adding an alpha nucleator during the polymerisation process significantly changes the crystallisation speed and shrinkage behaviour of the polymer. Faster crystallisation enables the cycle time to be reduced in injection moulding fittings which is particularly beneficial for the production of larger diameter fittings. The shrinkage of the products also becomes far less dependent on the colour additives, which enables faster colour changes during pipe extrusion without the need to make adjustments to the processing conditions.

 

https://www.pe100plus.com/PPCA/Developing-new-Multi-modal-Polypropylene-Random-Copolymer-PP-R-pipe-grades-to-meet-new-market-needs-p1424.html

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ADVANCING 1-HEXENE-BASED PP-RCT: PIPE APPLICATION EXAMPLES AND NEXT CHALLENGES

Simona Africano, Emanuele Burgin, Thomas Boehm

# 2021 Amsterdam

Since the ‘80s, Polypropylene-Random (PP-R) has been a material of choice for producing plastic pipes for Hot & Cold water installations. Compared to other polyolefins, PP-R has higher stiffness and higher temperature resistance, along with the typical advantages of plastic pipes such as light weight, fast and reliable jointing by welding, and chemical and corrosion resistance. In the light weighing perspective (reducing wall thickness without compromising the mechanical properties), the way we have recently implemented is co-polymerization of propylene with a new monomer, 1-Hexene. The polymers produced with 1-Hexene as co-monomer in a new, LyondellBasell proprietary technology, show a long term pressure resistance so increased to achieve MRS classification 12.5, hence PP125. In the 2012 ISO 15874 and in the 2017 ASTM F2389 revisions, the new PP-RCT designations has been introduced to differentiate the outperforming properties offered by the new PP’s. The 1-Hexene co-polymers meet those long term pressure resistance requirements.

This presentation reports several commercial examples of 1-Hexene based PP-RCT in Hot & Cold installations and in other industrial applications. In case of restructuring or refurbishing, the presentation includes a reference to the pipe material previously used and the reason customers are now selecting PP-RCT piping instead. The examples will be about private and public buildings, such as hotels, commercial districts and hospitals, located in various countries (mainly Europe), where in most of the cases the PP has been the material of choice thanks to the thermal, chemical and corrosion resistance.

The market implementation of PP-RCT has also indicated new challenges, the first of which for PP is Chlorine resistance (NaClO or ClO 2 ).Therefore a number of studies has been implemented in that respect. The presentation includes our latest findings and achievements so far. The unique creep resistance offered by the 1-Hexene comonomer has also allowed a development activity in other piping system areas, like Under Floor Heating or fittings, and increased output rate in the conventional PP-R applications. The presentation finally reports also an update on these new developments and concludes that after less than 10 years from the first industrial implementation, there is a great potential for 1-Hexene co-polymers in many piping applications to ultimately outperform the traditional metal based systems.

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CPVC application in the fire sprinkler system in China

Jiang Tongjun, Fu Zhimin, Yang Yuanjin

Papers # 2018 Las-Vegas

This paper introduces the application of CPVC pipe in fire sprinkler systems in China. The advantages and differences of CPVC pipe versus to galvanized steel pipes, the improvement of related laws and regulations and the market outlook are discussed. The overall result is a change in the upstream and downstream aspects of the CPVC fire sprinkler system application in China.

This paper introduces the application of CPVC fire sprinkler system pipe in China, the advantages and differences of using CPVC pipe versus galvanized steel pipes in this application and improvement of related laws as well as regulations. A review of the established design, installation, inspection, testing and national code of CPVC pipe used in fire sprinkler systems is included. An update is also provided on the content and progress of the national code under development for the manufacturing of CPVC products for fire sprinkler systems. Further, this paper presents the prospect for CPVC fire products in China’s market. From this review, one realizes, the overall result is a change in the upstream and downstream aspects of the CPVC fire sprinkler system application in China.

 

https://www.pe100plus.com/PPCA/CPVC-application-in-the-fire-sprinkler-system-in-China-p1657.html

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ANALYSIS OF PVC AND CPVC BLENDS

# 2021 Amsterdam

Unplasticized formulations based on Poly(Vinyl Chloride) (PVC) and Chlorinated Poly(Vinyl Chloride) (CPVC) resins offer technical solution to pressure piping systems that find extensive use in residential and industrial applications. Building upon the desirable properties of the vinyl monomer, the chlorine content of CPVC brings additional heat resistance and enhanced flame retardancy that extends its use in a wide variety of applications including hot water. Although PVC is also derived from the vinyl monomer, the properties of each material is to be respected. Formulations with blends of PVC and CPVC resins have been attempted but the compromise has to be taken into consideration. This paper will present analytical techniques such as Dynamic Mechanical Analysis (DMA) and Differential Scanning Calorimetry (DSC) to reveal the behavior of such blends whereas the results of bulk property testing can be misleading. Adherence to Cell Class targets (ASTM D1784 1 ) and meeting the required Hydrostatic Design Basis (HDB) (ASTM D2837 2 ) at elevated temperatures can be compromised.

https://www.pe100plus.com/PPCA/ANALYSIS-OF-PVC-AND-CPVC-BLENDS-p1806.html

 

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    PT SHUANGLIN PIPE INDONESIA is a joint venture subsidiary of Zhejiang Shuanglin Environment Co., Ltd. Our factory is located in CIKARANG, Indonesia. The plant covers an area of 4,000 square meters. Our company has introduced advanced production line and a professional production management team. The company mainly produces municipal and residential building water supply and drainage, sewage pipes and complete sets of systems. The product line includes HDPE/PP double-wall corrugated pipe and inspection wells for pipeline connection and other accessories.

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